The winners will face Wales.
Ukraine make their return to competitive football tonight.
They play their World Cup play-off semi-final with Scotland at Hampden Park.
The game had been delayed following Russia's invasion of Ukraine.
Kick off is at 7.45, with the winner set to take on Wales for a place in Qatar later this year.
Ahead of the World Cup play-off final on Sunday, Wales begin their Nations League campaign later.
They're away to Poland from 5pm.
Meanwhile, Wembley is the venue for the Finalassima between the European and Copa America champions.
Giorgio Chiellini will make his final appearance for Italy as they take on Argentina.
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